Pseudo-emulsion based hollow fibre strip dispersion (PEHFSD) technique is Investigated for the permeation–separation of chromium from hydrochloric acid media. The permeation of Cr(VI) is investigatedin relation to various experimental variables: hydrodynamic conditions, the concentration of Cr(VI) and HCl in the feed phase, Cyanex-923 concentration, hydrazine sulphate as the stripping agent in the pseudo-emulsion phase. The performance of the PEHFSD was analyzed and optimum conditions are suggested for chromium separation from simulated industrial waste in a hydrochloric acid media.